Thin film tandem perovskite solar cell pushes record

September 24, 2018 //By Nick Flaherty
Thin film tandem perovskite solar cell pushes record
imec in Belgium has developed a four-terminal thin-film tandem solar cell with a record efficiency of 24.6 percent using a perovskite top layer, opening up the use of the technology for solar films.

The tandem cell uses a top perovskite cell developed by imec as part of the EnergyVille and Solliance partnerships with a bottom CIGS cell from the Centre for Solar Energy and Hydrogen Research (ZSW) in 
Stuttgart, Germany. Tandem solar cells have been pushing conversion efficiencies higher but the thin film aspect is a key dfference.

The perovskite top cell in the tandem uses light in the visible part of the solar spectrum, while the light in the near-IR spectrum that passes through the perovskite cell is harvested by the underlying CIGS cell. In 
this way, the tandem cell significantly outperforms the stand-alone perovskite and CIGS cells. Both layers are also thin-film solar cells, paving the way to high efficiency flexible solar cells and building integrated photovoltaic (BIPV) solutions.

The 4-terminal tandem consists of a perovskite solar cell stacked on top of a CIGS cell, based on a fully scalable device concept to enable industrial adoption of the process. The transmittance of the perovskite cell for near-IR light was improved by adding optical coupling layers to the tandem stack and by optimizing the transparent electrodes. The perovskite itself was also optimized in terms of a wide bandgap of 1.72eV for higher tandem efficiency.

The CIGS cell of 0.5cm² size has been made at the high-efficiency line at ZSW, employing all optimized processes necessary for the preparation of thim film cells in volume. Further improvements of the technology will ultimately pave the way to thin-film tandem solar cells with efficiencies of more than 30 percent say researchers.

“We work on two types of tandem cells,” explains Tom Aernouts, group leader for thin-film photovoltaics at imec/EnergyVille. “We combine our state-of-the-art perovskite technology with silicon or CIGS bottom cells. The advantage of CIGS is that it is a thin-film technology, just like perovskite, and that the tandem cells therefore can be fabricated in a wide variety of shapes and sizes. This makes it possible to use this technology in building-integrated PV applications. Future work will focus on upscaling the technology

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