Solid-state battery uses lithium anode and hybrid electrolyte

March 05, 2019 // By Nick Flaherty
Solid-state battery uses lithium anode and hybrid electrolyte
Researchers from Forschungszentrum Jülich and the University of Münster in Germany have developed a new solid-state battery featuring an anode made of pure lithium.

Lithium is considered an ideal electrode material which can help achieve extremely high energy densities but is very reactive. Coating an lithium anode in two layers of a new polymer protects the ceramic electrolyte and prevent destructive metal deposits called dendrites that cause short circuits and fires.

"The goal was to expand our concept for a solid state battery to enable stable operation with a lithium anode, and we've done that," said Dr  Hermann Tempel from the Jülich Institute for Energy and Climate Research. 

Using lithium for the electrode created a solid-state battery with an energy density of 460 Wh/kg, almost twice that of current liquid lithium ion cells. The  solid-state batteries are also significantly less sensitive to temperature than conventional lithium-ion batteries and so do not need temperature management devices such as those used in electric cars so far, which should also save weight.

Construction of solid-state batteryDesign Solid-State Battery with Hybrid Electrolyte
S. Yu et al., J. Mater.  Chem. A, 2019, Advance Article, DOI: 10.1039 / C8TA11259B with slight modification (CC BY 3.0)

"The polymer functions like a protective layer, which makes the use of a lithium anode possible in the first place," said Tempel.  "It prevents the ceramic electrolyte from coming into direct contact with the metallic lithium at the anode.  This prevents damaging processes such as dendrite formation and chemical changes in the ceramic electrolyte, which impair the function of the battery. Initial tests in the laboratory have already been very successful.  There were hardly any performance losses over 500 charge and discharge cycles."

"The special thing about the cell is that it works despite the moderately conductive polymers;  In some ways even better than without," said Professor Hans-Dieter Wiemhöfer of the Helmholtz Institute Münster (HI MS), who has developed the special polymer that belongs to the class of polyphosphazenes.  He coordinates the MEET-HiEnD II project, from which the new battery emerged.

The polymer layer in the preparation is applied as a liquid

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