Inorganic perovskite absorber boosts thin-film solar cell production: Page 2 of 2

April 30, 2019 //By Christoph Hammerschmidt
Using inorganic persovskite materials in thin film solar cells
Researchers at Helmholtz-Zentrum in Berlin has developed a way to make it easier to use inorganic perovskite materials in thin-film solar cells.

The physicists designed an innovative experiment with which they could synthesize and analyze many material combinations within a single sample. By co-evaporation of cesium iodide and lead iodide, along with systematically varying the excess of elements in the atmosphere, they produced thin layers of CsPbI3. The substrate temperature was below 60 degrees Celsius. "Such a combinatorial research approach allows optimal production parameters for new material systems to be found much faster than in the conventional approach, which typically requires 100 samples to be produced for 100 compositions," explains Unold.

Their measurements show that both the structural and important optoelectronic material properties are sensitive to the relationship between cesium and lead. For example, an excess of cesium enables a stable perovskite phase with good mobility and lifetime of the charge carriers.

In cooperation with the junior research group of Prof. Steve Albrecht at the HZB, these optimized CsPbI3 layers were used to demonstrate perovskite solar cells with an efficiency of more than 12% and a stability of more than 1200 hours. "We have shown that inorganic perovskite absorbers could also be suitable for use in thin-film solar cells if they can be manufactured accordingly. We are currently working on the assumption that such components can still be very strongly optimized," says Unold.

onlinelibrary.wiley.com/doi/full/10.1002/aenm.201900555

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